In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33â (6) and 87.74â (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-Hâ¯N hydrogen bonds. In the crystal, an inter-molecular C-Hâ¯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by Ï-Ï stacking inter-actions [centroid-centroid distances = 3.739â (3)-3.776â (3)â à ] between the benzene rings of centrosymmetrically related mol-ecules.
6,6'-Dimeth-oxy-2,2'-[(E,E')-(2,4,6-trimethyl-1,3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate.
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作者:Bahron Hadariah, Bakar Najihah Abu, Yamin Bohari M, Yusof M Sukeri M
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Apr 1; 68(Pt 4):o1176 |
| doi: | 10.1107/S1600536812011531 | ||
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