The title compound, C(17)H(15)N(2)O(2) (+)·Cl(-)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethyl-formamide. The cationic benzimidazolium ring is connected to two furan rings via methyl-ene bridges. The furan rings make dihedral angle of 79.09â (18)° with respect to each other, and make dihedral angles of 73.92â (12) and 72.58â (13)° with respect to the benzimidazole ring. O-Hâ¯Cl, C-Hâ¯O and C-Hâ¯Cl hydrogen bonds and C-Hâ¯Ï inter-actions contribute to the stabilization of the crystal structure. Furthermore, there is a Ï-Ï inter-action between adjacent five- and six-membered rings of the benzimidazole groups [centroid-centroid distance = 3.5305â (8)â à ].
1,3-Difurfurylbenzimidazolium chloride monohydrate.
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作者:Akkurt Mehmet, Sireci Nihat, Deniz Selma, Küçükbay Hasan, Büyükgüngör Orhan
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Jul 29; 65(Pt 8):o2037-8 |
| doi: | 10.1107/S1600536809029626 | ||
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