In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex mol-ecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octa-hedrally coordinated by two chelating 2,2'-bipyridine ligands and two O atoms from the carboxyl-ate groups of two 2-(benzimidazol-2-ylsulfan-yl)acetate ligands. The two carboxyl-ate ligands adopt a cis configuration with respect to each other. Within each of these ligands, the imidazole fragments are bent back in a loop towards the acetyl groups, forming intra-molecular N-Hâ¯O hydrogen bonds, which help to stablilize the mononuclear complex. Adjacent mol-ecules are further linked by weak C-Hâ¯O hydrogen bonds, resulting in a chain along the c axis.
Bis[2-(benzimidazol-2-ylsulfan-yl)acetato]bis-(2,2'-bipyridine)cadmium(II).
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作者:Cheng Lin, Sun Yan-Yan, Wang Jian-Quan, Zhang Ya-Wen
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Oct 13; 65(Pt 11):m1356 |
| doi: | 10.1107/S1600536809039592 | ||
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