In the title compound, [PtCl2(C13H21N5)]·0.5CH3NO2, the Pt(II) atom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-tri-aza-penta-diene)Pt(II) metalla ring is slightly bent and does not conjugate with the aromatic ring. In the crystal, N-Hâ¯Cl hydrogen bonds link the complex mol-ecules, forming chains along [001]. The nitromethane solvent molecule shows half-occupancy and is disordered over two sets of sites about an inversion centre.
Di-chlorido-[N-(N,N-di-methyl-carbamimido-yl)-N',N',4-tri-methyl-benzohydrazonamide]-platinum(II) nitro-methane hemisolvate.
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作者:Bolotin Dmitrii S, Bokach Nadezha A, Haukka Matti
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Mar 12; 70(Pt 4):m131-2 |
| doi: | 10.1107/S1600536814003894 | ||
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