In the title compound, C35H32N4, the C-N bond lengths in the guanidine part are 1.286â (3), 1.387â (2) and 1.414â (2)â à , indicating double- and single-bond character. The N-C-N angles are 114.48â (17), 118.78â (17) and 126.72â (17)°, showing a deviation of the CN3 plane from an ideal trigonal-planar geometry. The carbazole ring system is almost planar (r.m.s. deviation = 0.002â à ). In the crystal, mol-ecules are connected by weak C-Hâ¯N hydrogen bonds, generating a zigzag chain along the ac plane. Weak Ï-Ï inter-actions [centroid-centroid distance = 3.785â (1)â à ] between two phenyl rings of the guanidine moiety are also present.
2-[4-(Carbazol-9-yl)phen-yl]-1,3-diethyl-1,3-di-phenyl-guanidine.
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作者:Tiritiris Ioannis, Kantlehner Willi
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jun 8; 69(Pt 7):o1066 |
| doi: | 10.1107/S1600536813014517 | ||
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