(2Z,2'Z)-Diethyl 3,3'-[butane-1,4-diylbis(aza-nedi-yl)]bis-(but-2-enoate).

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作者:Harrad Mohamed Anouar, Boualy Brahim, Ali Mustapha Ait, El Firdoussi Larbi, Stoeckli-Evans Helen
The whole mol-ecule of the title β-enamino-ester, C(16)H(28)N(2)O(4), is generated by a crystallographic inversion center, situated at the mid-point of the central C-C bond of the 1,4-diamino-butane segment. There are two intra-molecular N-H⋯O hydrogen bonds that generate S(6) ring motifs. This leads to the Z conformation about the C=C bonds [1.3756†(17)†à ]. The mol-ecule is S-shaped with the planar central 1,4-diamino-butane segment [maximum deviation for non H-atoms = 0.0058†(13)†à ] being inclined to the ethyl butyl-enonate fragment [C-C-O-C-C=C-C; maximum deviation = 0.0710†(12)†à ] by 15.56†(10)°. In the crystal, mol-ecules are linked via C-H⋯O inter-actions, leading to the formation of an undulating two-dimensional network lying parallel to the bc plane.

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