The whole mol-ecule of the title β-enamino-ester, C(16)H(28)N(2)O(4), is generated by a crystallographic inversion center, situated at the mid-point of the central C-C bond of the 1,4-diamino-butane segment. There are two intra-molecular N-Hâ¯O hydrogen bonds that generate S(6) ring motifs. This leads to the Z conformation about the C=C bonds [1.3756â (17)â à ]. The mol-ecule is S-shaped with the planar central 1,4-diamino-butane segment [maximum deviation for non H-atoms = 0.0058â (13)â à ] being inclined to the ethyl butyl-enonate fragment [C-C-O-C-C=C-C; maximum deviation = 0.0710â (12)â à ] by 15.56â (10)°. In the crystal, mol-ecules are linked via C-Hâ¯O inter-actions, leading to the formation of an undulating two-dimensional network lying parallel to the bc plane.
(2Z,2'Z)-Diethyl 3,3'-[butane-1,4-diylbis(aza-nedi-yl)]bis-(but-2-enoate).
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作者:Harrad Mohamed Anouar, Boualy Brahim, Ali Mustapha Ait, El Firdoussi Larbi, Stoeckli-Evans Helen
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Oct 1; 68(Pt 10):o2855-6 |
| doi: | 10.1107/S1600536812036823 | ||
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