In the title compound, C(14)H(12)N(4)O(5), an intra-molecular N-Hâ¯O hydrogen bond generates an S(6) ring motif. The dihedral angle between the two benzene rings is 3.91â (3)°, which shows the mol-ecule is almost planar. The para-nitro group is twisted from the benzene ring to which it is attached, making a dihedral angle of 8.50â (9)°. In the crystal structure, mol-ecules are linked together by inter-molecular C-Hâ¯O and inter-molecular three-centred Oâ¯O [2.8646â (12)-2.9213â (11)â à ] and Oâ¯N [3.0518â (11)â à ] inter-actions. The crystal structure is further stabilized by inter-molecular Ï-Ï inter-actions [centroid-to-centroid distances 3.5708â (6)-3.9728â (12)â à ].
2-Methoxy-benzaldehyde 2,4-dinitro-phenyl-hydrazone.
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作者:Fun Hoong-Kun, Kia Reza, Kargar Hadi
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Jan 8; 65(Pt 2):o246-7 |
| doi: | 10.1107/S1600536809000038 | ||
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