In the title solvate, C29H30N2O3·CHCl3, the dihedral angle between the indole ring system (r.m.s. deviation = 0.050â à ) and the 4-methyl-pyrrolidine ring is 88.88â (8)°. The latter ring adopts an envelope conformation with the N atom as the flap. Its mean plane makes dihedral angles of 86.94â (11) and 42.08â (9)° with the phenyl and di-methyl-benzene rings, respectively. The mol-ecular conformation is stabilized by intra-molecular C-Hâ¯O hydrogen bonds, which generate S(6) and S(9) ring motifs. The chloro-form solvent mol-ecule is linked to the organic mol-ecule by a C-Hâ¯O hydrogen bond involving the carbonyl O atom of the carboxyl-ate group. In the crystal, mol-ecules are linked via bifurcated N-Hâ¯(N,O) and C-Hâ¯O hydrogen bonds, forming chains propagating along [001].
Methyl 3'-(2,5-di-methyl-benz-yl)-1'-methyl-2-oxo-4'-phenyl-spiro-[indoline-3,2'-pyrrolidine]-3'-carboxyl-ate chloro-form monosolvate.
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作者:Karthikeyan S, Narayanan P, Sethusankar K, Devaraj Anthonisamy, Bakthadoss Manickam
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Feb 28; 70(Pt 3):o377-8 |
| doi: | 10.1107/S1600536814004073 | ||
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