In the crystal structure of the title compound, C(6)H(16)N(+)·C(20)H(12)O(4)P(-), an N-Hâ¯O inter-action links the cation to the anion. The N atom in the triethyl-ammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N-Hâ¯O inter-action with one phosphate O atom of the 1,1'-binaphthyl-2,2'-diyl phosphate ligand. A bifurcated C-Hâ¯O inter-action with the other phosphate O atom links molecules along the a axis. The dihedral angle between the two naphthyl ring systems is 58.92â (3)°. The refined Flack parameter value of 0.50â (10) indicates inversion twinning.
Triethyl-ammonium 1,1'-binaphthyl-2,2'-diyl phosphate.
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作者:Gowda Ravikumar R, Ramkumar Venkatachalam, Chakraborty Debashis
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jun 16; 66(Pt 7):o1625 |
| doi: | 10.1107/S160053681002026X | ||
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