In the title complex, [CuBr(2)(C(6)H(4)N(2)Se)(2)], the Cu(II) ion is tetra-coordinated by two bromide anions and two N atoms in a distorted square-planar geometry. The two essentially planar 2,1,3-benzoselenadiazole ligands [maximum deviations = 0.012â (2) and 0.030â (2)â à ] are approximately coplanar [dihedral angle = 6.14â (6)°]. In the crystal, short inter-molecular Seâ¯Br, Seâ¯N and Nâ¯N inter-actions are observed. These short inter-actions and inter-molecular C-Hâ¯Br hydrogen bonds link the complex mol-ecules into two-dimensional arrays parallel to the ac plane.
Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II).
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作者:Fun Hoong-Kun, Goh Jia Hao, Maity Annada C, Goswami Shyamaprosad
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jan 15; 67(Pt 2):m181-2 |
| doi: | 10.1107/S160053681005422X | ||
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