The title compound, (C(3)H(5)N(2))(4)[As(6)CuMo(6)O(30)], is made up of a centrosymmetric anionic cluster and four imidazolium cations. In the cluster, the central Cu(II) atom is six-coordinated and lies on an inversion center. Adjacent clusters are linked via N-Hâ¯O hydrogen bonds between the imidazole cations and polyoxidoanions into a three-dimensional supra-molecular architecture.
Tetra-imidazolium hexa-μ(4)-oxido-dodeca-μ(2)-oxido-dodeca-oxidohexa-arsenate(III)hexa-molybdenum(VI)cuprate(II).
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作者:Liu Meiduo, Su Zhanhua, Shang Yongchen
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Sep 30; 66(Pt 10):m1308 |
| doi: | 10.1107/S1600536810037414 | ||
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