In the structure of the title compound, C(20)H(18)N(4)O(2), the N-H and C=O bonds are trans to each other and the amide O atoms are syn to the ortho amino N atom in the benzoyl rings. The amide groups form dihedral angles of 8.4â (2) and 13.8â (2)° with their respective benzoyl rings, and dihedral angles of 51.85â (16) and 51.19â (17)° with the phenyl-enediamine ring. In the crystal, a centrosymmetric dimer is formed by inter-molecular N-Hâ¯O hydrogen bonds, resulting in an R(2) (2)(14) descriptor on a unitary level of graph-set analysis, and three intramolecular N-Hâ¯O bonds also occur.
2,2'-Diamino-N,N'-(o-phenyl-ene)di-benz-amide.
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作者:Booysen Irvin, Gerber Thomas I A, Hosten Eric, Mayer Peter
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Mar 25; 65(Pt 4):o850 |
| doi: | 10.1107/S1600536809009283 | ||
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