In the title imidazo[2,1-b][1,3,4]thia-diazole derivative, C(19)H(14)ClN(3)OS, the 4-methyl-benzyl and chloro-phenyl rings are inclined to the planar imidazo[2,1-b][1,3,4]thia-diazole moiety (r.m.s. deviation = 0.012â à ) by 64.5â (1) and 3.7â (1)°, respectively. The mol-ecular structure is primarily stabilized by a strong intra-molecular C-Hâ¯O hydrogen bond, leading to the formation of a pseudo-seven-membered S(7) ring motif, and a short intra-molecular C-Hâ¯N contact forming an S(5) ring motif. In the crystal, mol-ecules are linked by pairs of C-Hâ¯S hydrogen bonds, forming inversion dimers. The dimers are linked by C-Hâ¯O and C-Hâ¯Ï inter-actions, forming chains propagating along [110].
The crystal structure of 6-(4-chloro-phen-yl)-2-(4-methyl-benz-yl)imidazo[2,1-b][1,3,4]thia-diazole-5-carbaldehyde.
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作者:Sowmya A, Anil Kumar G N, Kumar Sujeet, Karki Subhas S
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2016 | 起止号: | 2016 Sep 23; 72(Pt 10):1460-1462 |
| doi: | 10.1107/S2056989016014754 | ||
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