In the title compound, C(27)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74â (5) and 68.23â (4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098â (2)â à .
N,N-Bis(diphenyl-phosphanyl)cyclo-propyl-amine.
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作者:Engelbrecht Ilana, Visser Hendrik G, Roodt Andreas
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Oct 23; 66(Pt 11):o2881 |
| doi: | 10.1107/S1600536810041711 | ||
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