The absolute configuration of the title compound, [Fe(C(5)H(5))(C(36)H(29)OP(2))], is S(p) at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal-pyramidal conformation. There is a short intra-molecular C-Hâ¯P contact with an Hâ¯P distance of 2.56â à . The hydr-oxy group is involved in an intra-molecular O-Hâ¯Ï(phen-yl) inter-action. The crystal packing shows five very weak inter-molecular C-Hâ¯Ï contacts, with Hâ¯Cg distances between 3.26 and 3.39â à (Cg is the centroid of a phenyl or cyclo-penta-dienyl ring).
(S)-1-Diphenyl-phosphanyl-2-{(S)-[2-(diphenyl-phosphan-yl)phen-yl]hydroxy-meth-yl}ferrocene.
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作者:Bats Jan W, Doppiu Angelino, Rivas Nass Andreas, Hashmi A Stephen K
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Nov 20; 64(Pt 12):m1585 |
| doi: | 10.1107/S1600536808038294 | ||
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