The title compound, C12H17N3OS, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the hydrazinecarbo-thio-amide group are 6.9â (4) and 37.2â (5)° in mol-ecules A and B, respectively. An intra-molecular O-Hâ¯N hydrogen bond is observed in each mol-ecule. This serves to maintain an approximately planar conformation for mol-ecule A, but leaves a significant twist between these two groups in mol-ecule B. In the crystal, a weak N-Hâ¯S inter-action is observed, forming inversion dimers among the B mol-ecules and resulting in an R 2 (2)(8) motif. These dimers are further inter-connected by weak N-Hâ¯O and C-Hâ¯O inter-molecular inter-actions, forming chains along [011].
N-Ethyl-2-[1-(2-hy-droxy-4-methyl-phen-yl)ethyl-idene]hydrazinecarbo-thio-amide.
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作者:Anderson Brian J, Hall Jeffrey R, Jasinski Jerry P
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 May 31; 70(Pt 6):o735 |
| doi: | 10.1107/S1600536814012203 | ||
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