The mol-ecule of the title ethanol solvate, C(15)H(21)N(3)O(6)·C(2)H(6)O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287â (3)â à ] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7â (2)°]. In the crystal, a network of O-Hâ¯O, O-Hâ¯N and N-Hâ¯O hydrogen bonds leads to the formation of supra-molecular arrays in the ab plane with the ethanol mol-ecules lying to the periphery on either side. Disorder in the solvent ethanol mol-ecule was evident with two positions being resolved for the C atoms [site occupancy of the major component = 0.612â (10)].
tert-Butyl N-{(1S)-1-[(2,4-dihy-droxy-benzyl-idene)hydrazinecarbon-yl]-2-hy-droxy-eth-yl}carbamate ethanol monosolvate.
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作者:Pinheiro Alessandra C, de Souza Marcus V N, Tiekink Edward R T, Wardell Solange M S V, Wardell James L
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Feb 9; 67(Pt 3):o581-2 |
| doi: | 10.1107/S1600536811003795 | ||
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