6-(Hex-5-en-yloxy)naphthalene-2-carb-oxy-lic acid.

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作者:Rahman Md Lutfor, Srinivasa H T, Mohd Yusoff Mashitah, Kwong Huey Chong, Quah Ching Kheng
The asymmetric unit of the title compound, C17H18O3, comprises three independent mol-ecules with similar geometries. In each mol-ecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0†(2), 1.05†(19)° and 1.5†(2)°. The butene group in all three mol-ecules are disordered over two sets of sites, with a refined occupancy ratio of 0.664†(6):0.336†(6). In the crystal, mol-ecules are oriented with respect to their carbonyl groups, forming head-to-head dimers via O-H⋯O hydrogen bonds. Adjacent dimers are further inter-connected by C-H⋯O hydrogen bonds into chains along the a-axis direction. The crystal structure is further stabilized by weak C-H⋯π inter-actions.

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