The Te(IV) atom in the title compound, [Te(C(4)H(9))(C(8)H(10)Br)Cl(2)] or C(12)H(19)BrCl(2)Te, is in a distorted Ï-trigonal-bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48â (4)°]. Close intra-molecular [Teâ¯Br = 3.3444â (18)â à ] and inter-molecular [Teâ¯Cl = 3.675â (3)â à ] inter-actions are observed. The latter lead to centrosymmetric dimers which assemble into layers in the bc plane. The primary connections between layers are of the type C-Hâ¯Cl.
1-[(Z)-1-Bromo-2-(butyl-dichloro-λ-tellan-yl)ethen-yl]cyclo-hex-1-ene.
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作者:Zukerman-Schpector Julio, Caracelli Ignez, Guadagnin Rafael Carlos, Stefani Hélio A, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jul 1; 67(Pt 7):o1751-2 |
| doi: | 10.1107/S1600536811023142 | ||
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