In the title compound, C(15)H(17)NOS·H(2)O, the benzene and pyridine rings form a dihedral angle of 71.18â (2)°. The intra-molecular Sâ¯O distance [2.737â (3)â à ] is shorter than expected and, in terms of hybridization principles, the N-C-S angle [114.1â (2)°] is smaller than expected. The crystal structure is stabilized by inter-molecular O-Hâ¯O and weak C-Hâ¯O hydrogen bonds. In addition, weak Ï-Ï stacking inter-actions with a centroid-centroid distance of 3.778â (3)â à are also observed.
2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate.
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作者:Ravindran Durai Nayagam B, Jebas Samuel Robinson, Johnson Jeyakumar H, Schollmeyer Dieter
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Sep 17; 64(Pt 10):o1952 |
| doi: | 10.1107/S1600536808029255 | ||
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