The title compound, [CoCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], crystallizes as a monomeric complex. The coordination environment around the Co(II) center could be described as a distorted octa-hedron consisting of three N donors from the facially coordinating triaza macrocyclic ligand, one O donor from dimethyl-formamide and two Cl(-) ions. Neutral complex mol-ecules are associated via inter-molecular C-Hâ¯Cl hydrogen bonds to form two-dimensional layers. C-Hâ¯O hydrogen bonds are also present.
Dichlorido(dimethyl-formamide-κO)[1,4,7-tris-(2-cyano-ethyl)-1,4,7-triaza-cyclo-nonane-κN,N,N]cobalt(II).
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作者:Zhang Zhong, Geng Zhi-Rong, Zhao Qun, Wang Zhi-Lin
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Jul 19; 64(Pt 8):m1041-2 |
| doi: | 10.1107/S160053680802179X | ||
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