In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-Hâ¯S hydrogen bonds, forming a three-dimensional network structure.
Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II).
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作者:Zhou Xiu-Xia, Zhou Zheng-Yuan, Chen Jian-Qiao, Lin Xiao-Ming, Cai Yue-Peng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Jan 9; 64(Pt 2):m328-9 |
| doi: | 10.1107/S1600536807068493 | ||
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