In the title complex, [Fe(II)Fe(III) 2(C9H10BN6)2(CN)6(CH3OH)4]·2CH3OH, two [Fe(III)(Tp)(CN)3](-) anions [Tp is hydro-tris-(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)4](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O-Hâ¯O and O-Hâ¯N hydrogen bonds involving the uncoordinated methanol solvent mol-ecules, forming a three-dimensional network.
Di-μ-tricyanido-tetra-cyanidobis[hydro-tris-(pyrazoylborato)]tetra-methanol-diiron(III)iron(II) di-methanol disolvate.
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作者:Zhang Kuirun, Sato Osamu
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Jan 22; 70(Pt 2):m56 |
| doi: | 10.1107/S1600536814001019 | ||
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