catena-Poly[(dichloridocadmium)-di-μ-chlorido-[bis-(morpholinium-κO)cadmium]-di-μ-chlorido].

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作者:Wang Wen-Xiang, Dai Jing
In the title compound, [Cd(2)Cl(6)(C(4)H(10)NO)(2)](n), the coordination geometry of each Cd(II) ion is distorted octa-hedral, but with quite different coordination environments. One Cd(II) atom is coordinated by four Cl atoms and two O atoms from two morpholinium ligands, while the other is coordinated by six Cl atoms. Adjacent Cd(II) atoms are inter-connected alternately by paired chloride bridges, generating a chain parallel to the a axis. Inter-chain N-H⋯Cl inter-actions form a two-dimensional network.

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