In the title compound, C(16)H(10)Cl(2)F(3)N(3)S, the dihedral angle between the quinoline and thio-phene ring systems is 4.94â (10)°. The NH group of the hydrazone moiety does not form a hydrogen bond, due to a steric crowding. In the crystal, the thio-phene ring takes part in weak Ï-Ï stacking inter-actions with the pyridine ring [centroid-to-centroid separation = 3.7553â (19)â à and inter-planar angle = 5.48â (12)°] and the benzene ring [3.7927â (19)â à and 4.58â (12)°]. Together, these lead to [100] stacks of mol-ecules in an alternating head-to-tail arrangement, with two Ï-Ï stacking contacts between each adjacent pair.
(E)-1-(2,5-Dichloro-thio-phen-3-yl)ethan-one [8-(trifluoro-meth-yl)quinolin-4-yl]hydrazone.
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作者:Dayananda A S, Yathirajan H S, Harrison William T A, Slawin Alexandra M Z
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Mar 1; 68(Pt 3):o790 |
| doi: | 10.1107/S1600536812005673 | ||
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