In the title compound, {[Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·2H(2)O}(n), the Cd(II) atom is seven-coordinated by two N atoms from the phenanthroline-derived 4,5-diaza-fluorene-9-one ligand, two O atoms from one bidentate benzene-1,3-dicarboxyl-ate ligand and three O atoms from the three water mol-ecules in a distorted penta-gonal-bipyramidal arrangement. Moreover, there are two dissociative water mol-ecules in each unit. Neighbouring units inter-act through Ï-Ï inter-actions [centroid-centroid distances = 3.325â (3) and 3.358â (4)â à ] and O-Hâ¯O hydrogen-bonding, resulting in a two-dimensional network extending parallel to (001).
catena-Poly[[[triaqua-(4,5-diaza-fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl-ato] dihydrate].
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作者:Li Xiao-Ping, Fang Wei, Mei Ze-Min, Jin Xiang-Jun, Qi Wen-Liang
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Aug 15; 65(Pt 9):m1069-70 |
| doi: | 10.1107/S1600536809031237 | ||
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