Bis{2,2'-[methyl-aza-nediylbis(methyl-ene)]bis-(4,6-dimethyl-phenolato)-κ(3) O,N,O'}titanium(IV) toluene sesquisolvate.

The title compound, [Ti(C19H23NO2)2]·1.5C7H8, crystallizes with one titanium complex mol-ecule per asymmetric unit together with one and a half toluene mol-ecules. The Ti(IV) atom is coordinated by two fully deprotonated O,N,O'-tridentate phen-oxy-amine ligands in a distorted octa-hedral environment. Within this arrangement the O atoms occupy the equatorial sites and the N atoms the axial sites. One of the toluene mol-ecules is disordered over two sets of sites in a 0.628†(18):0.372†(18) ratio.