In the title compound, C(32)H(26)Cl(2)N(2)O(3), the piperidone ring adopts a chair conformation and the proline and pyrrolidine rings adopt envelope conformations. The indane ring system is essentially planar with an r.m.s. deviation of 0.011â à for the non-H atoms. The dihedral angle between the two chloro-substituted benzene rings is 63.69â (10)°. Intra-molecular C-Hâ¯O and N-Hâ¯O hydrogen bonds may influence the mol-ecular conformation. In the crystal structure, mol-ecules are connected into layers by weak inter-molecular C-Hâ¯O hydrogen bonds.
19-[(E)-4-Chloro-benzyl-idene]-16-(4-chloro-phen-yl)-2-hydr-oxy-1,11-diaza-hexa-cyclo-[15.3.1.0.0.0.0]henicosa-3(8),4,6-triene-9,18-dione.
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作者:Kumar Raju Suresh, Osman Hasnah, Abdul Rahim Aisyah Saad, Hemamalini Madhukar, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 May 26; 66(Pt 6):o1444-5 |
| doi: | 10.1107/S1600536810018611 | ||
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