In the title compound, (C(10)H(10)NO)(2)[Ni(C(7)H(3)NO(4))(2)]·CH(3)OH·H(2)O, the coordination geometry of the Ni(II) atom can be described as distorted octa-hedral. In the crystal, noncovalent inter-actions play an important role in the stabilization of the structure, involving O-Hâ¯O, N-Hâ¯O and weak C-Hâ¯O hydrogen bonds and Ï-Ï stacking inter-actions between the pyridine rings of the pyridine-2,6-dicarboxyl-ate ligands [centroid-centroid distance = 3.7138â (15)â à ] and between the 8-hy-droxy-2-methyl-quinolinium cations [centroid-centroid distances = 3.6737â (15), 3.4434â (14), 3.6743â (15), 3.7541â (16), 3.5020â (15) and 3.7947â (15)â à ].
Bis(8-hy-droxy-2-methyl-quinolinium) bis-(pyridine-2,6-dicarboxyl-ato)-nickelate(II) methanol monosolvate monohydrate.
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作者:Aghabozorg Hossein, Gholizadeh Ahmad, Mirzaei Masoud, Notash Behrouz, Moshki Niloofar
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jul 1; 67(Pt 7):m891-2 |
| doi: | 10.1107/S1600536811021015 | ||
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