The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra-hedral geometries, although the bridging Fe-O-Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation. In the crystal, the components are linked by C-Hâ¯Cl and C-Hâ¯O inter-actions.
N,N'-Dibutyl-N,N,N',N'-tetra-methyl-ethane-1,2-diaminium μ-oxido-bis-[trichloridoferrate(III)].
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作者:Närhi Sari M, Kostamo Jatta, Asikkala Janne, Oilunkaniemi Raija, Laitinen Risto S
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Jun 1; 68(Pt 6):m748 |
| doi: | 10.1107/S1600536812019964 | ||
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