Iodido-bis-(morpholine-4-carbodi-thio-ato-κ(2) S,S')(1,10-phenanthroline-κ(2) N,N')bis-muth(III).

The title compound, [Bi(C4H8NOS2)2I(C12H8N2)], is monomeric, with the Bi(III) atom chelated by the two S atoms of two morpholine-4-carbodi-thio-ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi(III) atom adopting a highly distorted monocapped octa-hedral geometry.