In the crystal structure of the title compound, [Zn(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Zn(H(2)O)(3) entities with one carboxyl-ate group of the furan-2,5-dicarboxyl-ate ligand. Adjacent chains are linked by O(water)-Hâ¯O hydrogen-bonding inter-actions. The Zn(H(2)O)(3)O(3) polyhedron displays a distorted octa-hedral geometry with one weak Zn-O(carboxyl-ate) coordination [2.433â (8) A°] and two water mol-ecules located in axial positions. Except for one of the axial water molecules and two adjacent H atoms, the other atoms (including H atoms) possess site symmetry m.
catena-Poly[(triaqua-zinc)-μ-furan-2,5-dicarboxyl-ato-κ(3)O(2):O(2),O(2')].
阅读:8
作者:Li Ya-Feng, Gao Yue, Xu Yue, Qin Xiao-Lin, Gao Wen-Yuan
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Apr 1; 68(Pt 4):m500 |
| doi: | 10.1107/S1600536812012111 | ||
特别声明
1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。
2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。
3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。
4、投稿及合作请联系:info@biocloudy.com。
