In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-Hâ¯Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa-hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.
Tripyridinium cis-tetra-chlorido-dioxido-molybdate(VI) chloride.
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作者:Fernandes José A, Gomes Ana C, Figueiredo Sónia, Gago Sandra, Ribeiro-Claro Paulo J A, Gonçalves Isabel S, Almeida Paz Filipe A
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jun 26; 66(Pt 7):m862-3 |
| doi: | 10.1107/S1600536810023950 | ||
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