The mol-ecule in the structure of the title compound, C(15)H(11)ClN(2)OS, displays two planar residues [r.m.s. deviation = 0.014â à for the benzimidazole residue, and the ketone group is co-planar with the benzene ring to which it is attached forming a O-C-C-C torsion angle of -173.18â (14) °] linked at the S atom. The overall shape is based on a twisted V, the dihedral angle formed between the two planes being 82.4â (2) °. The amine-H atom is bifurcated, forming N-Hâ¯O and N-Hâ¯S hydrogen bonds leading to dimeric aggregates. These are linked into a supra-molecular chain along the c axis via C-Hâ¯Ï hydrogen bonds. Chains form layers in the ab plane being connected along the c axis via weak Ï-Ï inter-actions [3.9578â (8)â à ] formed between centrosymmetrically related chloro-substituted benzene rings.
2-(1H-1,3-Benzodiazol-2-ylsulfan-yl)-1-(4-chloro-phen-yl)ethanone.
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作者:Abdel-Aziz Hatem A, Ng Seik Weng, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Oct 1; 67(Pt 10):o2639 |
| doi: | 10.1107/S160053681103666X | ||
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