In the title complex, [Ag(NO3)(C10H9N3)4], the nitrate ligand is found to be disordered over two sets of positions, with occupancy factors of 0.473â (5) and 0.527â (5). The Ag(I) ion is located in a square-pyramidal coordination environment formed by four N atoms from four bis-(pyridin-2-yl)amine ligands and one O atom from a nitrate ligand. Weak inter-actions between the Ag(I) ions and the nitrate anions acting in a monodentate mode [Agâ¯O = 2.791â (13) and 2.816â (9)â à for the major component of the nitrate ligand, and 2.865â (8) and 2.837â (8)â à for the minor component] link the complex mol-ecules into a chain along [001]. N-Hâ¯O hydrogen bonds are observed.
Tetra-kis[bis-(pyridin-2-yl)amine-κN (2)](nitrato-κO)silver(I).
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作者:Parashchenko Yuliia, Pavlishchuk Anna, Bokach Nadezhda A, Haukka Matti
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Jan 22; 70(Pt 2):m58-9 |
| doi: | 10.1107/S1600536814000907 | ||
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