In the title compound, C(6)H(10)N(6)S(2) (2+)·2Cl(-)·CH(3)OH, the pyrid-azine ring is almost planar, the greatest deviation from the mean plane being 0.025â (2)â à for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87â (6) and 57.94â (7)°. The thiouronium cations and the chloride anions are linked by strong N-Hâ¯Cl hydrogen bonds. The methanol solvent mol-ecule inter-acts with both the chloride ion (through an O-Hâ¯Cl hydrogen bond) and the cation (through an N-Hâ¯O hydrogen bond), resulting in a three-dimensional supra-molecular arrangement.
S,S'-(Pyridazine-3,6-di-yl)dithio-uronium dichloride methanol monosolvate.
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作者:Hübscher Jörg, Izotova Lidiya, Talipov Samat, Katzsch Felix, Weber Edwin
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jun 1; 67(Pt 6):o1477 |
| doi: | 10.1107/S1600536811018514 | ||
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