In the title compound, C15H14ClNO2S2, the 2H-chromene ring system is essentially planar, with a maximum deviation of 0.0133â (10)â à . Three C atoms and their attached H atoms of the pyrrolidine ring are disordered [occupany ratio 0.874â (7):0.126â (7)] with both disorder components adopting a twisted conformation. The dihedral angle between the 2H-chromene ring system and the major occupancy component of the pyrrolidine ring is 89.45â (7)°. In the crystal, inversion dimers linked by pairs of C-Hâ¯S and C-Hâ¯O inter-actions generate R (2) 2(24) and R (2) 2(10) loops, respectively. Further C-Hâ¯O hydrogen bonds link the dimers into [100] chains. C-Hâ¯Ï inter-actions also occur and there is very weak Ï-Ï stacking [inter-planar spacing = 3.650â (5)â à ; centroid-centroid distance = 4.095â (7)â à ] between inversion-related chloro-benzene rings.
(7-Chloro-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodi-thio-ate.
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作者:Kotresh O, Devarajegowda H C, Shirahatti Arunkumar, Kumar K Mahesh, Mahabhaleshwaraiah N M
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Oct 23; 69(Pt 11):o1684-5 |
| doi: | 10.1107/S1600536813028080 | ||
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