In the title compound, C(20)H(16)F(2)O(2), the cyclo-hex-2-en-1-one ring adopts a distorted envelope conformation and the dihedral angles between its six-atom mean plane and the fluorophenyl rings are 38.9(8) and 82.3(1)°. The two fluoro-phenyl rings are oriented at an angle of 77.3â (3)°. The long hy-droxy O-H bond length of 1.22â (3) and the Hâ¯O distance of 1.28â (3)â à , together with a longer than expected C=O bond length [1.290â (2)â à ] in the hy-droxy(en-1-one) group, indicate sharing of the H atom as Oâ¯Hâ¯O between the two O atoms and the influence of electron delocalization. Weak C-Hâ¯O inter-molecular inter-actions form an infinite two-dimensional network in (011).
(6Z)-3,5-Bis(4-fluoro-phen-yl)-6-(1-hy-droxy-ethyl-idene)cyclo-hex-2-en-1-one.
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作者:Jasinski Jerry P, Golen James A, Samshuddin S, Narayana B, Yathirajan H S
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Mar 1; 68(Pt 3):o638-9 |
| doi: | 10.1107/S1600536812003078 | ||
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