Two independent thio-urea derivatives comprise the asymmetric unit of the title compound, C(14)H(20)N(2)OS. The major difference between the mol-ecules relates to a twist in the relative orientation of the benzene rings [torsion angles = 4.5â (2) and -19.9â (2)° for the two independent mol-ecules]. The thio-carbonyl and carbonyl groups lie to opposite sides of the mol-ecule as there are twists about the central N-S bond [torsion angles = 83.90â (15) and 81.77â (15)°]. Supra-molecular chains extending parallel to [101] with a stepped topology and mediated by N-Hâ¯O hydrogen bonding feature in the crystal structure. C-Hâ¯O and C-Hâ¯Ï inter-actions are also present.
1-Benzoyl-3,3-bis-(propan-2-yl)thio-urea.
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作者:Gunasekaran N, Karvembu R, Ng Seik Weng, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jul 24; 66(Pt 8):o2113 |
| doi: | 10.1107/S1600536810028862 | ||
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