In the title compound, C(27)H(20)BrNO(3), two intra-molecular C-Hâ¯O hydrogen bonds both form S(6) rings. The pyrrolidine ring adopts a twisted conformation about the C-C bond bearing the indane ring systems. The other two five-membered rings within the indane systems are in shallow envelope conformations, with the spiro C atoms as the flap atoms. The mean plane of the pyrrolidine ring [maximum deviation = 0.275â (1)â à ] makes dihedral angles of 65.25â (7), 78.33â (6) and 75.25â (6)° with the bromo-substituted benzene ring and the mean planes of the mono- and dioxo-substituted indane rings, respectively. In the crystal, mol-ecules are linked by C-Hâ¯O and C-Hâ¯N hydrogen bonds into a three-dimensional network. In addition, C-Hâ¯Ï inter-actions are observed.
4'-(3-Bromo-phen-yl)-1'-methyl-dispiro-[indan-2,2'-pyrrolidine-3',2''-indan]-1,3,1''-trione.
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作者:Wei Ang Chee, Ali Mohamed Ashraf, Choon Tan Soo, Arshad Suhana, Razak Ibrahim Abdul
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Oct 1; 68(Pt 10):o2907-8 |
| doi: | 10.1107/S1600536812037993 | ||
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