The title compound, C(20)H(17)N(3)O(2)·CH(4)O·H(2)O, was synthesized by the condensation reaction of 2-benzyl-oxybenzaldehyde with isoniazid (isonicotinic acid hydrazide). The tricyclic compound displays a trans configuration with respect to the C=N double bond. The central benzene ring makes dihedral angles of 8.83â (7) and 70.39â (8)° with the pyridine ring and the terminal benzene ring, respectively. The dihedral angle between the pyridine ring and the terminal benzene ring is 73.11â (8)°. In the crystal structure, mol-ecules are connected by inter-molecular N-Hâ¯O, O-Hâ¯O, O-Hâ¯(N,N) and C-Hâ¯O hydrogen bonds, forming a two-dimensional network perpendicular to the a axis.
(E)-N'-(2-Benzyl-oxybenzyl-idene)isonicotinohydrazide methanol solvate monohydrate.
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作者:Naveenkumar H S, Sadikun Amirin, Ibrahim Pazilah, Hemamalini Madhukar, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 May 15; 66(Pt 6):o1337-8 |
| doi: | 10.1107/S1600536810016958 | ||
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