In the title centrosymmetric binuclear Cd(II) compound, [Cd(2)(C(7)H(5)O(3))(4)(C(6)H(6)N(2)O)(2)]·4H(2)O, the six-coordinated Cd(II) atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl-ate groups. In the crystal, O-Hâ¯O, N-Hâ¯O and C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network. Ï-Ï Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770â (1), 3.769â (1) and 3.632â (1)â à ] may further stabilize the structure.
Bis(μ-3-hy-droxy-benzoato)-κO,O:O;κO:O,O-bis-[(3-hy-droxy-benzoato-κO,O')(iso-nicotinamide-κN)cadmium] tetra-hydrate.
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作者:Zaman Ibrahim Göker, Caylak DelibaÅ Nagihan, NecefoÄlu Hacali, Hökelek Tuncer
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Feb 1; 68(Pt 2):m198-9 |
| doi: | 10.1107/S160053681200219X | ||
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