In the title compound, C(21)H(23)N(3)O, the dihedral angles formed by the pyrazolone ring with two phenyl rings are 10.38â (8) and 76.94â (6)°. The sec-butyl-amino group is disordered over two positions, with refined site-occupancy factors of 0.730â (4) and 0.270â (4). The compound could potentially be ligand stabilized in the solid state in a keto-enamine tautomeric form. The amine functionality is involved in an intra-molecular N-Hâ¯O hydrogen bond, while weak inter-molecular C-Hâ¯O and C-Hâ¯N hydrogen bonds participate in the formation of the crystal structure.
4-{(Z)-(sec-Butyl-amino)(phen-yl)methyl-ene}-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one.
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作者:Xu Hai-Zhen, Xu Jian-Ping, Yuan Yan-Wei, Zhang Jin, Zhu You-Quan
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Aug 8; 65(Pt 9):o2116 |
| doi: | 10.1107/S160053680902950X | ||
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