The title compound, C21H17N3O3, is a new polymorph of an already published structure [Shashidhar et al. (2006 â¶). Acta Cryst. E62, o4473-o4475]. The previously reported structure crystallizes in the monoclinic space group C2/c, whereas the structure reported here is in the tetra-gonal space group I41/a. The bond lengths and angles are similar in both structures. The mol-ecule adopts an extended conformation via intra-molecular N-Hâ¯O and O-Hâ¯N hydrogen bonds; the terminal phenyl ring and the hy-droxy-lphenyl ring are twisted with respect to the central benzene ring by 44.43â (7) and 21.99â (8)°, respectively. In the crystal, mol-ecules are linked by N-Hâ¯O hydrogen bonds, weak C-Hâ¯O hydrogen bonds and weak C-Hâ¯Ï inter-actions into a three-dimensional supra-molecular network.
A new polymorph of N-(2-{N'-[(1E)-2-hy-droxy-benzyl-idene]hydrazinecarbon-yl}phen-yl)benzamide.
阅读:5
作者:Mohamed Shaaban K, Mague Joel T, Akkurt Mehmet, Potgieter Herman, Albayati Mustafa R
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 May 10; 70(Pt 6):o645-6 |
| doi: | 10.1107/S1600536814010010 | ||
特别声明
1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。
2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。
3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。
4、投稿及合作请联系:info@biocloudy.com。
