In the title compound, C(18)H(13)ClFN(3)O(2), the pyrrolidine ring adopts an envelope conformation and the planar part is rotated by 4.3â (6)° from the plane of the benzene ring and is almost perperdicular both to the diazo-acetyl unit [dihedral angle = 78.93â (7)°] and the phenyl ring [dihedral angle = 86.07â (7)°]. In the crystal, mol-ecules are linked into a three-dimensional framework by C-Hâ¯O inter-actions. The mol-ecular conformation is stabilized by an intra-molecular C-Hâ¯O hydrogen bond.
1-(3-Chloro-4-fluoro-phen-yl)-5-(2-diazo-acet-yl)-4-phenyl-pyrrolidin-2-one.
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作者:Ray Jayanta Kumar, Haldar Pranab, Canle L M, Fernández P M I, Santaballa J A
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jul 24; 66(Pt 8):o2103 |
| doi: | 10.1107/S1600536810024657 | ||
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