The fused five- and three six-membered rings of the anthra[1,2-d]imidazole-trione part of the title compound, C27H20N4O4, show two different substituents at the imidazole N atoms, viz. an allyl group and a [3-(pyridin-4-yl)-4,5-di-hydro-isoxazol-5-yl]methyl group. The fused-ring system is approximately planar [r.m.s. deviation = 0.232â (2)â à ], but is slightly buckled along the common edge of the two pairs of adjacent rings, with a dihedral angle between them of 11.17â (6)°. The isoxazole ring makes dihedral angles of 27.2â (2) and 12.7â (2)° with the imidazole and pyridine rings, respectively. Weak C-Hâ¯O and C-Hâ¯N hydrogen bonds ensure the cohesion of the crystal structure, forming a three-dimensional network.
1-(Prop-2-en-1-yl)-3-{[3-(pyridin-4-yl)-4,5-di-hydro-isoxazol-5-yl]meth-yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione.
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作者:Afrakssou Zahra, Kandri Rodia Youssef, Capet Frédéric, Essassi El Mokhtar, Rolando Christian, El Ammari Lahcen
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 May 22; 69(Pt 6):o945-6 |
| doi: | 10.1107/S160053681301369X | ||
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