The asymmetric unit of the title compound, C(14)H(17)NO(4)·1.25H(2)O, consists of four substituted pyrrolidone mol-ecules (two pairs of enanti-omers) and five water mol-ecules. The five-membered rings each have an envelope conformation, with the C atom bonded to the ester group as the flap. The mean planes of the five-membered rings of the four pyrrolidone mol-ecules make dihedral angles of 60.87â (5), 64.45â (5), 62.03â (5) and 65.79â (5)° with respect to the phenyl rings. In the crystal, the pyrrolidone and water mol-ecules are connected through O-Hâ¯O hydrogen bonds, forming a layer parallel to the ab plane. The two-dimensional network is further stabilized by inter-molecular C-Hâ¯O hydrogen bonds.
Ethyl 4-hy-droxy-1-methyl-5-oxo-2-phenyl-pyrrolidine-3-carboxyl-ate 1.25-hydrate.
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作者:Mansor Nurul Shulehaf, Mohammat Mohd Fazli, Shaameri Zurina, Khaledi Hamid
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Feb 1; 69(Pt 2):o293-4 |
| doi: | 10.1107/S1600536813001943 | ||
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