The conformation of the title compound, C(34)H(26)F(2)O(6), is cone-shaped, partially determined by intra-molecular C-Hâ¯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10â (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49â (8)°. In the crystal, mol-ecules are linked by C-Hâ¯O and C-Hâ¯F hydrogen bonds, forming a three-dimensional supra-molecular structure. There are also C-Hâ¯Ï contacts present within the framework structure.
Crystal structure of (6E,20E)-3,24-di-fluoro-13,14,28,29-tetra-hydro-5H,22H-tetra-benzo[e,j,p,u][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione.
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作者:Mohamed Shaaban K, Akkurt Mehmet, Hawaiz Farouq E, Ayoob Mzgin M, Hosten Eric
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2017 | 起止号: | 2017 Jan 1; 73(Pt 1):13-16 |
| doi: | 10.1107/S2056989016018934 | ||
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