Crystal structure of 2,2-dimethyl-N-(5-methyl-pyridin-2-yl)propanamide.

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作者:El-Hiti Gamal A, Smith Keith, Hegazy Amany S, Alanazi Saud A, Kariuki Benson M
There are two mol-ecules in the asymmetric unit of the title compound, C11H16N2O. The pyridine rings and amide groups overlap almost perfectly (r.m.s. overlay fit = 0.053†à ), but the tertiary butyl groups have different orientations: in one mol-ecule, one of the methyl C atoms is syn to the amide O atom [O-C-C-C = -0.8†(3)°] and in the other the equivalent torsion angle is 31.0†(2)°. In the crystal, the two independent mol-ecules are linked by a pair of N-H⋯N hydrogen bonds in the form of an R 2 (2)(8) loop to form a dimer. A C-H⋯O inter-action connects the dimers into [100] chains.

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