There are two mol-ecules in the asymmetric unit of the title compound, C11H16N2O. The pyridine rings and amide groups overlap almost perfectly (r.m.s. overlay fit = 0.053â à ), but the tertiary butyl groups have different orientations: in one mol-ecule, one of the methyl C atoms is syn to the amide O atom [O-C-C-C = -0.8â (3)°] and in the other the equivalent torsion angle is 31.0â (2)°. In the crystal, the two independent mol-ecules are linked by a pair of N-Hâ¯N hydrogen bonds in the form of an R 2 (2)(8) loop to form a dimer. A C-Hâ¯O inter-action connects the dimers into [100] chains.
Crystal structure of 2,2-dimethyl-N-(5-methyl-pyridin-2-yl)propanamide.
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作者:El-Hiti Gamal A, Smith Keith, Hegazy Amany S, Alanazi Saud A, Kariuki Benson M
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2015 | 起止号: | 2015 May 23; 71(Pt 6):o419-20 |
| doi: | 10.1107/S2056989015009378 | ||
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