In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa-hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl-glyoxime and dimethyl-glyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intra-molecular O-Hâ¯O hydrogen bonds are observed between the dimethyl-glyoxime and dimethyl-glyoximate ligands. Mol-ecules are linked into a chain running along the [101] direction by O-Hâ¯O and C-Hâ¯Cl hydrogen bonds. The chains are cross-linked through inter-molecular C-Hâ¯Cl hydrogen bonds.
Dichlorido(dimethyl-glyoximato-κN,N')(dimethyl-glyoxime-κN,N')cobalt(III).
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作者:Ramesh P, Subbiahpandi A, Jothi P, Revathi C, Dayalan A
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Jan 4; 64(Pt 2):m300-1 |
| doi: | 10.1107/S1600536807068407 | ||
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